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Fluorescence properties of nonconductive organic small molecule nano-films prepared by DC sputtering method

机译:通过DC溅射法制备的非导电有机小分子纳米膜的荧光性能

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The key to preparing nano-films by DC (Direct Current) sputtering is to prepare the film materials into targets. Organic small molecule fluorescent materials (such as 1, 4-Bis(2-cyanostyryl) benzene, to be noted as ER-I) are usually not conductive, and it is not possible to make the elements as targets. Therefore, there are some difficulties in preparing the organic materials into films by DC sputtering. In this paper, we fabricated ER-I nano-films by using the DC sputtering method, and their fluorescence properties are significantly different from those of powder materials. The fluorescence emission spectra of the films prepared by the DC sputtering method have an apparent bimodal morphology. Compared with the ER-I powder material, the fluorescence emission peak has a blue shift of 5 nm and 22 nm. To study the luminescence mechanism of the films, we further investigated the fluorescence properties of the films after thermal treatment and analyzed the structure and surface morphology of the films by XRD and SEM. This paper provides a new idea and method for the preparation of organic nano-films and has a potential application value in the preparation of organic light-emitting films and soft optics devices.
机译:通过DC(直流)溅射制备纳米膜的关键是将薄膜材料制备成靶标。有机小分子荧光材料(例如1,4-双(2-氰基(2-氰基)苯,待注意为ER-1)通常不导电,并且不可能使元件作为靶标。因此,通过DC溅射将有机材料制备成薄膜存在一些困难。在本文中,我们通过使用DC溅射方法制造了ER-I纳米膜,并且它们的荧光性能与粉末材料显着不同。通过DC溅射法制备的薄膜的荧光发射光谱具有表观双峰形态。与ER-I粉末材料相比,荧光发射峰具有5nm和22nm的蓝色偏移。为了研究薄膜的发光机制,我们进一步研究了热处理后薄膜的荧光特性,并通过XRD和SEM分析了薄膜的结构和表面形态。本文提供了用于制备有机纳米膜的新思想和方法,并且在制备有机发光膜和软光学器件方面具有潜在的应用值。

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