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Impact of Changing Microstructural Compositions of Lime Based Mortar on Flexibility: Case Study of Sustainable Lime-Cement Composites

机译:基于石灰基砂浆的微观结构组成对灵活性的影响:可持续石灰水泥复合材料的案例研究

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Lime mortar, an age-long building material is primarily popular for its flexibility, the basis of its ability to accommodate masonry deformation, hence durability. However, lime’s characteristic delayed setting/hardening time, low mechanical strength and poor internal cohesion often characterised by volumetric changes have put its use into decline. These shortcomings have therefore relegated relevance of this fundamental flexibility feature which underscores limes’ excellent performance and durability characteristics. The research therefore attempted to leverage this feature through evaluation of synergised lime composites, using cement as a partial replacement for lime. This is with a view to integrating advantageous features of ‘lime and cement’ as a composite, at the expense of their known individual drawbacks. The methodology involved mortars with the same Binder/Aggregate (B/A) mix ratio (1:3) using five different compositions of ‘cement-lime’ binders (i.e. 1:1, 1:2, 1:3, 2:1 and 3:1). The research focused on comparative evaluations of each composition in both fresh and hardened states, with the latter covering twelve-month curing period. While Water/Binder ratio constituted the fresh state assessment parameters, mechanical characteristics and microstructural features were evaluated in the hardened state. Results of the investigation show that progressive addition of cement significantly changes pore size distribution (PSD) of lime mortar from predominant pore sizes between (0.5 – 5 μm) and (5 – 20 μm) into (10 nm – 2 μm) range. This alteration is associated with porosity reduction by up to 11%. Significant improvements in the mechanical strengths of the composite is recorded as both the compressive and flexural strengths of the composite with 75% of cement is 18 and 6 times higher respectively, compared with the reference mortar. However, progressive addition of cement is proportional to the E-value of the composite (with a clear linear relationship), leaving a negative impact on the flexibility. Nonetheless, all the composites investigated exhibit elastic behaviours relative to the basic lime mortar. In particular, composite with cement addition up to 33% of the binder compositions exhibits deformation tendencies under compression. However, mortars with higher cement compositions (i.e. above 33%) would strain linearly until failure occurs suddenly with minimal deformation. Substitution of lime with cement therefore has a significant impact on the microstructural compositions of lime mortar, and subsequent improvement on the performance of the composite. Despite the improved mechanical strengths, inherent flexibility of lime is maintained though negatively impacted, subject to the amount of lime substituted. Hence, relative to specific purposes, lime revival can be promoted in form of sustainable lime-cement composites.
机译:Lime Martar,一个长长的建筑材料主要是由于其灵活性的流行,基础是其适应砌体变形的能力,因此耐用。然而,石灰的特征延迟设定/加固时间,低机械强度和差的内部内聚力通常是体积变化的特征,使其使用变为下降。因此,这些缺点使得这一基本灵活性的相关性得到了极大的灵活性,强调了石浆的优异性能和耐用性特征。因此,研究试图通过评估协同的石灰复合材料来利用这种特征,使用水泥作为石灰的部分替代品。这是为了以其已知的单个缺点将“石灰和水泥”的有利特征集成为复合材料。该方法涉及使用相同的粘合剂/聚集体(B / A)混合比(1:3)的砂浆使用五种不同的“水泥 - 石灰”粘合剂(即1:1,1:2,1:3,2:1和3:1)。研究重点是新鲜和硬化状态中每种组合物的比较评估,后者占据了12个月的固化期。虽然水/粘合剂比例构成了新的状态评估参数,但在硬化状态下评估了机械特性和微观结构特征。调查结果表明,水泥的逐步加入显着改变了从(0.5-5μm)和(5-20​​μm)之间的主要孔尺寸(0.5-20μm)中的主要孔尺寸的石灰砂浆的孔径分布(PSD)。这种改变与孔隙率降低至11%有关。与参考砂浆相比,复合材料的机械强度的显着改进记录为75%水泥的复合材料的压缩和弯曲强度分别为18和6倍。然而,水泥的逐步添加与复合材料的电子值(具有清晰的线性关系)成比例,对灵活性产生负面影响。尽管如此,所有复合材料都研究了相对于基本石灰砂浆的表现出的弹性行为。特别地,具有水泥添加的复合材料高达33%的粘合剂组合物在压缩下表现出变形倾向。然而,具有更高水泥组合物的砂浆(即33%)将线性稳定,直到突然发生故障,变形最小。因此,利石用水泥取代对石灰砂浆的微观结构组成具有显着影响,以及随后改善复合材料的性能。尽管有改善的机械强度,但虽然受到替代的石灰的量,但虽然对石灰的量受到负面影响,但耐石灰的固有灵活性。因此,相对于特定目的,可以以可持续的石灰水泥复合材料的形式促进石灰复复复合材料。

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