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Modeling of disperse dye adsorption on modified polyester fibers

机译:分散染料吸附在改性聚酯纤维上的建模

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The results of the research on the ability of adsorption of dye on polyester fibers at atemperature of 98 °C are presented in this paper. The fibers were previously modified inaqueous solutions of NaOH, KOH or Al(OH)3. Typically, the dyeing of the fibers takesplace at high temperatures and under pressure in the presence of the carrier. Previousprocessing before adsorption-dyeing, alkali hydrolysis, changes the surface morphologyof polyester fibers. Based on dye exhaustion results, it was found that the dye adsorptionon modified polyester fibers (degree of exhaustion 18.2 %, for a dye concentration of 200mg?dm-3 and adsorption time of 5 min) has been bigger than adsorption to unmodifiedfibers (degree of exhaustion 10 %, for a dye concentration of 200 mg?dm-3 and adsorptiontime of 5 min). The five-parameter nonlinear model of Fritz-Schlunder is the most efficient in simulating isothermal adsorption of disperse dye on polyester fibers (the correlation coefficient is 0.995). Other adsorption models, Dubinin-Radushkevich, Marczewski-Jaroniec and Hill give poorer results and cannot be used to explain the adsorption ofthe disperse dye for polyester fibers (the correlation coefficients are 0.891, 0.922 and0.973, respectively).
机译:本文介绍了染料在涤纶纤维上吸附染料能力的研究结果。纤维预先改性NaOH,KOH或Al(OH)3的含量溶液。通常,纤维的染色在载体存在下在高温下和压力下呈现。在吸附 - 染色之前,碱水解在碱性水解中的先前改变聚酯纤维的表面形态学。基于染料耗尽结果,发现染料吸附剂改性聚酯纤维(枯竭程度为18.2%,染料浓度为200mgΔdm-3和5分的吸附时间)大于对未经修补胶质的吸附(度疲惫的10%,染料浓度为200mg?DM-3和5分钟的吸附时间)。 Fritz-Schlunder的五参数非线性模型是模拟聚酯纤维上分散染料的等温吸附最有效的(相关系数为0.995)。其他吸附模型,Dubinin-Radushkevich,Marczewski-Jaroniec和Hill给出较差的结果,不能用于解释聚酯纤维的分散染料的吸附(相关系数为0.891,0.922和0.973)。

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