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Anti-Graffiti Coatings on Stones for Historical Buildings in Turin (NW Italy)

机译:都灵历史建筑的石头涂层涂鸦涂层(NW意大利)

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The application of anti-graffiti products to stones belonging to architectural heritage is a common procedure that is currently complementary to traditional graffiti removal treatments, such as chemical and mechanical cleaning. In this study, two anti-graffiti coatings (a sacrificial product and a permanent one) were tested on four stones (with a different texture, mineralogy, and surface finish) commonly found in the historical city center of Turin (Italy). In order to evaluate the effectiveness of the anti-graffiti products, the removal of two graffiti paints with different compositions was tested. The results of the cleaning procedures performed on the surfaces coated with anti-graffiti products were evaluated, considering both the graffiti remains and the alterations induced on the surface. Chemical cleaning based on the use of a low-toxic ternary solvent mixture was applied on the unprotected stones for a comparison with the results obtained on the surfaces coated with anti-graffiti products. The samples were observed under stereomicroscopy and ultraviolet fluorescence photography and all of the treated surfaces were evaluated by roughness measurements, the contact sponge method, static contact angle measurements, and scanning electron microscopy. The composition of the anti-graffiti product, the graffiti paint to be cleaned, and the remover recommended by the manufacturer proved to be key factors for the cleaning effectiveness achieved on coated surfaces. Moreover, to a lesser extent, the mineralogy, texture, and surface finish of the stone also influenced the results of the cleaning procedures. The sacrificial anti-graffiti product enhanced the cleaning effectiveness on all stones if compared to uncoated surfaces; however, the permanence of coating remains on the surface after cleaning proved to be critical. Regarding the use of the permanent anti-graffiti products, intense disparate results were achieved, depending on the graffiti paint composition.
机译:抗涂鸦产品在属于建筑遗产的石头中的应用是一种常见的程序,目前与传统的涂鸦去除处理互补,如化学和机械清洁。在这项研究中,在历史城市中心(意大利)的四块石头(具有不同的质地,矿物学和表面处理)上测试了两个抗涂鸦涂料(牺牲产品和永久性)。为了评估抗涂鸦产品的有效性,测试了两种具有不同组成的涂鸦涂料的去除。评估在涂有抗涂鸦产品的表面上进行的清洁程序的结果,考虑到涂鸦仍然存在,并在表面上诱导的改变。基于使用低毒三元溶剂混合物的化学清洗施加在未受保护的石头上,与涂覆有抗涂鸦产品的表面上获得的结果进行比较。在立体镜检查下观察样品,并通过粗糙度测量,接触海绵法,静态接触角测量和扫描电子显微镜评估所有处理表面。抗涂鸦产品的组成,涂鸦涂料待清洁,制造商建议的搬运工被证明是在涂层表面上达到的清洁效果的关键因素。此外,在较小程度上,石头的矿物学,质地和表面光洁度也影响了清洁程序的结果。如果与未涂覆的表面相比,牺牲抗涂鸦产品在所有石头上提高了所有石块的清洁效果;然而,清洁被证明是关键的情况下,涂层的持续仍然存在于表面上。关于使用永久性抗涂鸦产品,取决于涂鸦涂料组合物,实现了强烈的不同结果。

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