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Self-Healing UV Curable Acrylate Coatings for Wood Finishing System, Part 1: Impact of the Formulation on Self-Healing Efficiency

机译:用于木材整理系统的自愈UV可固化丙烯酸酯涂料,第1部分:配方对自我愈合效率的影响

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In the wood flooring sector, good surface mechanical properties, such as abrasion and scratch resistance, are prerequisite. Surface wood protection is provided by finishing systems. Despite coating improvement, scratches formation on wood flooring is unavoidable. A new approach to increase service life is to confer the self-healing property to the finishing system. The most common coatings used for prefinished wood flooring are acrylate UV curable 100% solids coatings. They usually have good mechanical properties and high cross-linking density. The objective of this study was to develop and evaluate an intrinsic self-healing formulation, which is applicable to wood flooring. For this purpose, acrylate formulations were developed with monomers and oligomers carrying hydroxyl groups. To meet the requirements of wood application, hardness, and polymerization conversion of coatings were evaluated. K?nig pendulum damping tests provide information on coating hardness and flexibility. Results around 80 oscillations is acceptable for UV curable wood sealer. The chemical composition was studied by FT-IR spectroscopy while dynamical mechanical analysis (DMA) was performed to determine glass transition temperature and cross-linking density. The self-healing behavior was evaluated by gloss and scratch depth measurements. The formulation’s composition impacted the hydrogen binding quantity, the conversion, the Tg and the cross-linking density. The (hydroxyethyl)methacrylate (HEMA) monomer provided self-healing and acrylated allophanate oligomer allowed self-healing and cross-linking. This study demonstrated that it is possible to combine high cross-linking density and self-healing property, using components with low steric hindrance.
机译:在木地板部门中,表面机械性能,如磨损和耐刮擦性,是先决条件。表面木材保护由整理系统提供。尽管涂层改进,但木地板上的划痕是不可避免的。一种提高使用寿命的新方法是将自我修复的属性赋予整理系统。用于预制木地板的最常见的涂层是丙烯酸酯UV可固化100%固体涂料。它们通常具有良好的机械性能和高交联密度。本研究的目的是开发和评估内在的自我愈合配方,适用于木地板。为此目的,丙烯酸酯配方用载体羟基的单体和低聚物进行开发。为了满足木材应用,硬度和涂料的聚合转化的要求。 k?nig摆动阻尼试验提供有关涂覆硬度和柔韧性的信息。结果紫外线固化木质密封剂可接受80个振荡。通过FT-IR光谱研究化学组成,同时进行动力学机械分析(DMA)以确定玻璃化转变温度和交联密度。通过光泽和划伤深度测量来评估自我愈合行为。制剂的组合物影响了氢结合量,转化率,Tg和交联密度。 (羟乙基)甲基丙烯酸酯(HEMA)单体提供自愈合和丙烯酸酯的寡聚体允许自愈合和交联。该研究表明,使用具有低空间阻断的组分可以结合高交联密度和自愈性。

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