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Chemical composition analysis on industrial scale ingots and castings of TiAl alloys

机译:工业规模锭和铸件铸件的化学成分分析

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摘要

The chemical composition variation of the TiAl-4722 alloys was examinedin a batch of the industrial scale master ingots, and in the corresponding castingsprepared by conventional vacuum arc remelting (VAR) combined with induction skullmelting (ISM) and investment casting processes. The content changes of majorelements and interstitial elements were evaluated based on the chemical analysisat the top and bottom of the ingots and castings. Results show that the contents ofC, N, H, Fe and Si have almost no change in the ingots and castings, suggestingthat the chemical analysis on these elements can be based on the batch analysis.The O content keeps almost the same in different ingots, but exhibits relatively largedifferences in castings, which was probably influenced by the reaction between the shellmold and the molten alloy, and the spalling of face coat of the shell mold during casting.For the major elements of Al, Nb and Cr, the composition difference between the topand the bottom of the ingots is less than that of the castings. But for the O element, thetrend is different, especially for the castings, suggesting that the investment casting is ahomogenization process for Cr and Nb, but a differentiation process for O. The contentsof major elements in castings fluctuate mainly in the same range as that in the ingots,indicating that the contents of the major elements are controllable during investmentcasting.
机译:TiAl-4722合金的化学成分变化在一批工业尺度晶锭中进行了检查,并在相应的铸件中通过常规真空弧重熔(VAR)与感应Skullmelting(ISM)和投资铸造工艺一起制备。基于化学分析的顶部和铸件的化学分析评估了马球和间质元素的内容变化。结果表明,铸锭和铸件几乎没有变化的含量,暗示这些元素的化学分析可以基于批量分析。o内​​容在不同的锭中保持几乎相同,但是在铸件中表现出相对较大的铸件,这可能受到壳体和熔融合金之间的反应的影响,以及在铸造期间壳体模具的面罩的剥落。对于Al,Nb和Cr的主要元素,组成差异铸锭的底部小于铸件的底部。但对于O元素,浓度是不同的,特别是对于铸件,表明投资铸造是Cr和Nb的Ahomuenging方法,而是O的分化过程。铸件主要元素的内容主要在相同的范围内波动指示铸锭,表明主要元素的内容在投资期间可控。

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