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Oxygen fugacity of Alto Paranaíba kimberlites and diamond instability: Três Ranchos IV and Limeira I intrusions

机译:Altoparanaíba金伯利特和钻石不稳定的氧气抗不稳定:三个牧场IV和Limeira I Intrings

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Oxygen fugacity (?O2) conditions were established for Três Ranchos IV (TR-IV, diamond-bearing) and Limeira I (LM-I, barren) kimberlite intrusions, in Alto Paranaíba Alkaline Province, to constrain a possible correlation between fO2 and diamond instability. Temperature and pressure estimates obtained from the xenocryst assemblage composition are compatible up to garnet lherzolite levels. It suggests that both intrusions could cross the diamond-stability field. The ?O2 of the TR-IV constrained by perovskite oxygen barometry presents an average value of -2.4 for ΔNNO, with standard deviation of 1.30 (n = 120), whereas those calculations for LM-I have an average value of -1.31 for ΔNNO, with standard deviation of 1.38 (n = 81). Considering these uncertainties, there is an important superposition of fO2 values for both intrusions, in which there is higher tendency of more reduced conditions for TR-IV. For the LM-I, an oxybarometer based on the composition of monticellite yielded a similar ΔNNO range: -4.2 and +2.5. Some crystals and samples present trends towards more reduced conditions, while others display more oxidized conditions for each intrusion. Due to the superposition of ranges and absence of a preferential trend, the influence of fO2 for the possible instability of diamonds in the study area remains uncertain.
机译:为TrêsRanchosIV(TR-IV,钻石)和Limeira I(LM-I,贫瘠)Kimberlite Intrings建立了氧气逃避(o2)条件,在Altoparanaíba碱省,以限制Fo2和钻石之间的可能相关性不稳定。从XenoCryst组合组合物中获得的温度和压力估计均相容于石榴石LherzoLite水平。它表明,两种入侵都可以越过菱形稳定场。由钙钛矿氧气气压测量约束的TR-IV的o2呈平均值为-2.4的ΔnnO,标准偏差为1.30(n = 120),而LM-i的计算具有平均值-1.31的Δnno ,标准偏差为1.38(n = 81)。考虑到这些不确定性,两种入侵的FO2值具有重要叠加,其中TR-IV的更低趋势更低。对于LM-I,基于Monticellite的组成的氧气仪产生了类似的ΔnNO范围:-4.2和+ 2.5。一些晶体和样品存在趋势,趋势更低的条件,而其他晶体对每个侵入的抗氧化病症。由于范围的叠加和没有优先趋势,FO2对研究区域中可能不稳定性的FO2的影响仍然不确定。

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