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Infrared spectra of methanol desorption in a He stream and under vacuum on CeO2 and ZrO2 catalyst surfaces

机译:红外光谱在HE流中的甲醇解吸和在CeO2和ZrO2催化剂表面的真空下

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摘要

Infrared spectra of methanol desorption in a He stream and under vacuum on CeO _(2) and ZrO _(2) catalyst surfaces are added for the article ( RSC Adv. , 2014, 4 , 30968) as a response to the letter of Dr F. C. Meunier ( RSC Adv. , 2016, 6 , 17288) and to make the ascription of the bands at 1096, 1054, 1032 and 1012 cm ~(?1) more convincing. After putting under vacuum, the bands at 1096, 1054, 1032 and 1012 cm ~(?1) still exist, which indicates that these bands are ascribed to chemisorbed methoxy.
机译:在HE流中甲醇解吸的红外光谱和在CEO _(2)和ZrO _(2)催化剂表面上的真空下,为物品(RSC ADV。,2014,4,30968)作为对DR博士信函的回应FC Meunier(RSC ADV。,2016,6,17288)并制作1096,1054,1032和1012 cm〜(?1)的频段的归档更加令人信服。在真空下放置后,仍然存在1096​​,1054,1032和1012cm〜(β1)的带仍然存在,这表明这些带均匀于化学吸附甲氧基。

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