Synthesis of Au-decorated three-phase-mixed TiO2/phosphate modified active carbon nanocomposites as easily-recycled efficient photocatalysts for degrading high-concentration 2,4-DCP

摘要

It is of great significance to fabricate easily-recycled TiO _(2) photocatalysts with high activity. Herein, dominant-anatase three-phase (anatase/rutile/brookite)-mixed nanosized TiO _(2) with high photocatalytic activity for degrading a high-concentration of 2,4-DCP has been synthesized via a hydrothermal process with HCl as a phase-directing agent, and interestingly the apparent photoactivity could be greatly improved by decorating Au nanoparticles and then coupling phosphate-treated active carbon. The amount-optimized nanocomposite displays ～12-fold enhancement in degradation rate constant ( k ) compared to anatase TiO _(2) . Based on the steady-state surface photovoltage spectra, fluorescence spectra related to the produced ·OH amount, temperature-programmed desorption and O _(2) electrochemical reduction curves, it is confirmed that the exceptional photoactivity is mainly attributed to the greatly-enhanced charge separation from the phase-mixed composition, and from the decorated Au as electron acceptors and its promotion effects on O _(2) activation. Moreover, the use of phosphate-modified AC as a support is also positive for efficient photocatalytic reactions by accepting electrons and concentrating the pollutants, with recyclable features. This work provides a feasible strategy to fabricate TiO _(2) -based nano-photocatalysts for degrading high-concentration pollutants to remediate the environment.