Magnetic and microwave properties of SrFe 12O 19/MCe 0.04Fe 1.96O 4 (M = Cu, Ni, Mn, Co and Zn) hard/soft nanocomposites

摘要

This paper reports the synthesis, structural characteristics and magnetism of SrFe12O19/MCe0.04Fe1.96O4(M = Cu, Ni, Mn, Co and Zn) hard/soft nanocomposites. The hard/soft compositions were manufactured via aone-potreactions citrate sol-gel approach. The hard/soft phases formation was confirmed using XRD, SEM, TEM and HRTEM techniques.M vs. H(Magnetization measurements) were done at unbent temperature and 10 K. SmoothedMagainstHloops and single peaks indM/dH vs. Hcurves were noticed in SrFe12O19/MnCe0.04Fe1.96O4, SrFe12O19/CuCe0.04Fe1.96O4and SrFe12O19/ZnCe0.04Fe1.96O4hard/soft nanocomposites. This indicated the manifestation of well exchange-coupled effect among hard and soft phases in these composites. However, SrFe12O19/CoCe0.04Fe1.96O4and SrFe12O19/NiCe0.04Fe1.96O4hard/soft nanocomposites showed non-well smoothedMagainstHloops and two peaks indM/dHversusHplots, indicating that the dipolar interactions are unimportant compared to exchange-coupling behavior. Among all prepared nanocomposites, the SrFe12O19/MnCe0.04Fe1.96O4hard/soft nanocomposite showed the highest exchange-coupling behavior. Microwave properties of the SrFe12O19/MCe0.04Fe1.96O4(M = Cu, Ni, Mn, Co and Zn) hard/soft nanocomposites were investigated using coaxial method with applied frequency values fall between 2 and 18 GHz. Reflection losses were calculated from frequency dependences of the imaginary and real parts of permeability and permittivity. The correlation between the chemical composition of the spinel phase (A-cation) and microwave properties of composites. Most intensive electromagnetic absorption was observed for Ni- and Mn-spinels. This is can be a result of the differences in electron shell configuration and radii for A-site ions in the spinel phase. Change of the absorption mechanisms (transition from ionic polarization to dipole polarization) was observed.