A novel and stable ultraviolet and infrared intensity sensor in impedance/capacitance modes fabricated from degraded CH 3NH 3PbI 3- xCl x perovskite materials

摘要

The present situation of COVID-19 diverted our focus towards utilizing the degraded solar cells for sensor application, this will help in global energy harvesting. So, here is our successful effort to reuse already degraded solar cells as ultraviolet (UV) and infrared (IR) sensor. The spin-coated perovskite (CH3NH3PbI3-XClX) has been already tested for visible light spectrum, as an extension to that now it is utilized as UV and IR intensity sensors to cover the whole spectrum. The employed CH3NH3PbI3-XClXmaterial was used after its efficiency loss has been reached to a saturation point in photovoltaic devices. Each deposited layer was investigated from UV to the IR absorption spectrum for deepening study through UV–vis spectroscopy. In the sandwiched architecture possessing FTO/PEDOT: PSS/Perovskite/PC61BM/CdS/Au symmetry, the perovskite film has been employed as an absorbent layer, however, other layers participation also plays a key role. The resultant device yielded very good sensing performance because of the enhanced excitons generation which is attributed to the precise selection of the interfacial materials, e.g. CdS and PC61BM as an ETM and PEDOT: PSS as HTM. The impedance and capacitance of the devices within 0.01?200?kHz under varied UV and IR illumination intensities were investigated. Measurements showed that as the intensity of the light increased i.e., UV (0–200?W/m2) and IR (0–5800?W/m2), impedance decreased while capacitance increased. The current results are attributed to the increase in the concentration of charges i.e., electron-hole pairs generation depending on the built-in capacitance and frequency of the charges.