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Development of Polypropylene-Based Single-Polymer Composites With Blends of Amorphous Poly-Alpha-Olefin and Random Polypropylene Copolymer

机译:基于聚丙烯的单聚合物复合材料,具有无定形聚α-烯烃和随机聚丙烯共聚物的共混物

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We developed polypropylene-based single-polymer composites (PP-SPC) with blends of amorphous poly-alpha-olefin (APAO) and random polypropylene copolymer (rPP) as matrix material and polypropylene (PP) woven fabric as reinforcement. Our goal was to utilize the lower melting temperature of APAO/rPP blends to increase the consolidation of the composites and decrease the heat load of the PP reinforcement. We produced the composites by film-stacking at 160 °C, and characterized the composites with density, peel, static tensile and dynamic falling weight impact tests, and by scanning electron microscopy. The results indicate that consolidation can be enhanced by increasing the APAO content of the matrix. We found that the APAO content of 50% is optimal for tensile properties. With increasing APAO content, the perforation energy decreased, but even the well-consolidated composites showed very high perforation energy. In the case of a pure APAO matrix, fiber content can be increased up to 80 wt% without a severe loss of consolidation, resulting in good tensile properties. The PP-SPCs developed possessed excellent mechanical properties, and well-consolidated composites can be produced with APAO/rPP blends as a matrix with high fiber content.
机译:我们开发了基于聚丙烯的单聚合物复合材料(PP-SPC),其具有非晶多α-烯烃(APAO)和随机聚丙烯共聚物(RPP)作为基质材料和聚丙烯(PP)织物作为增强物的共混物。我们的目标是利用Apao / RPP混合物的较低熔化温度,以增加复合材料的固结并降低PP加固的热负荷。我们通过在160℃下叠加薄膜制备复合材料,并用密度,剥离,静态拉伸和动态下降的重量冲击试验以及通过扫描电子显微镜的复合材料。结果表明通过增加基质的aao含量可以增强固结。我们发现50%的APAO含量是拉伸性能的最佳状态。随着APAO含量的增加,穿孔能量降低,但甚至良好的复合材料均显示出非常高的穿孔能量。在纯APAO基质的情况下,纤维含量可以增加高达80wt%而不会严重损失固结,导致良好的拉伸性能。所开发的PP-SPC具有优异的机械性能,并且可以用Apao / RPP共混物作为具有高纤维含量的基质制备良好的合成材料。

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