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Influence of the Solution-Treatment Temperature and Short Aging Times on The Electrochemical Corrosion Behaviour of Uns S32520 Super Duplex Stainless Steel

机译:溶液处理温度和短老化时间对智能S32520超双相不锈钢电化学腐蚀行为的影响

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摘要

Sigma phase leads to deterioration of corrosion resistance of super duplex stainless steels (SDSS) and its volume fraction increases as the time which the materials is exposed in determined temperature increases. In the present study, the effect of the short aging time on the formation of the sigma phase and on the corrosion behavior of UNS S32520 SDSS at 3.5% sodium chloride solution was evaluated using microstructural characterization, linear potentiodynamic polarization curve and electrochemical impedance spectroscopy. The results indicated that the SDSS sample solution-treated at 1150oC and aged at 850oC for 5 min may improve the corrosion resistance in comparison with the as-received and solution-treated conditions, due to the better partition of the elements Cr, Mo and dissolution of certain amount of sigma phase in the microstructure. However, results also showed that when SDSS solution-treated at 1150oC is aged at 850oC with the aging time slightly superior (10 min), the precipitation of sigma phase increases leading to a rapid deterioration of the corrosion resistance of the material.
机译:Sigma相导致超级双相不锈钢(SDSS)的耐腐蚀性的劣化,并且其体积分数随着材料暴露在确定的温度升高的时间上而增加。在本研究中,使用微观结构表征评估了微观结构表征,线性电位动力学偏振曲线和电化学阻抗光谱法评估了短老化时间对Sigma相对形成的影响和对3.5%氯化钠溶液的腐蚀行为的影响。结果表明,在1150℃下处理的SDS样品在850℃下处理5分钟,可以改善与接受和溶液处理的条件相比的耐腐蚀性,因为元素Cr,Mo和溶解更好地分配在微观结构中一定量的σ相。然而,结果还表明,当在1150℃下处理的SDSS溶液在850℃下稍微优越(10分钟)时,Sigma相的沉淀导致材料耐腐蚀性的快速劣化。

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