Fe3O4-Loaded g-C3N4/C-Layered Composite as a Ternary Photocatalyst for Tetracycline Degradation

摘要

A ternary photocatalyst, Fe_(3)O_(4)-loaded g-C_(3)N_(4)/C-layered composite (g-C_(3)N_(4)/C/Fe_(3)O_(4)) was fabricated by a facile sonication and in situ precipitation technique. Carbon nanosheets were prepared using the remaining non-metallic components of waste printed circuit boards as carbon sources. In this hybrid structure, g-C_(3)N_(4) was immobilized on the surfaces of carbon nanosheets to form a layered composite, and 10–15 nm Fe_(3)O_(4) nanoparticles are uniformly deposited on the surface of the composite material. The photocatalytic performance of the catalyst was studied by degrading tetracycline (TC) under simulated sunlight. The results showed that the photoactivity of the g-C_(3)N_(4)/C/Fe_(3)O_(4) composite to TC was significantly enhanced, and the degradation rate was 10.07 times higher than that of pure g-C_(3)N_(4), which was attributed to Fe_(3)O_(4) nanoparticles and carbon nanosheets. Carbon sheets with good conductivity are an excellent electron transporter, which promotes the separation of photogenerated carriers and the Fe_(3)O_(4) nanoparticles can utilize electrons effectively as a center of oxidation–reduction. Moreover, a possible photocatalytic mechanism for the excellent photocatalytic performance was proposed.