Experimental and Modeling Process Optimization of Lead Adsorption on Magnetite Nanoparticles via Isothermal, Kinetics, and Thermodynamic Studies

摘要

Lead has been a burgeoning environmental pollutant used in industrial sectors. Therefore, to emphasize the reactivity of lead toward magnetite nanoparticles for their removal, the present study was framed to analyze mechanisms involved in adsorption of lead. Batch adsorption studies have shown remarkable adsorption efficiency with only a 10 mg adsorbent dose used to extract 99% Pb~(2+) (110 mg L~(–1)) within 40 min at pH 6. Isothermal, kinetic, and thermodynamic studies were conducted, and the equilibrium data was best fit for the Langmuir isotherm model with a maximum of 41.66 mg g~(–1) adsorption capacity at 328 K. Moreover, a pseudo second order was followed for adsorption kinetics and thermodynamic parameters such as Gibbs energy (ΔG °), enthalpy (ΔH °), and entropy (ΔS °) that were calculated and revealed the spontaneous, feasible, and exothermic nature of the process.