Calcium-Loaded Municipal Sludge-Biochar as an Efficient and Stable Catalyst for Biodiesel Production from Vegetable Oil

摘要

In this contribution, biochar from municipal sludge was used as a novel matrix for the synthesis of a series of calcium-based heterogeneous catalysts toward biodiesel production. Their catalytic activity was investigated in terms of catalyst loading and calcination temperature during preparation, in addition to the transesterification parameters including the methanol/oil molar ratio, reaction time, and catalyst amount. The highest biodiesel yield up to 93.77% was achieved with the 30Ca/A-SBC-700, and it maintained as high as 84.9% even after 10 cycles of a consecutively alternating catalysis and regeneration process. It was revealed that the porous municipal sludge biochar and autologous SiO_(2) were accountable for the superior stability of the present catalyst. This work may provide a new path to value-added valorization of sludge waste and also a renewable and efficient catalyst for biodiesel production at a low cost.