KOH-Activated Geopolymer Microspheres Recycle Co(II) with Higher Adsorption Capacity than NaOH-Activated Ones

摘要

A new type of absorbent with high efficiency was synthesized by KOH-activated slag-based geopolymer microspheres (K-SGM), which exhibited higher adsorption capacities for recycling Co(II) (Q _(e,K-SGM) = 192.31 mg/g, Q _(e,Na-SGM) = 91.21 mg/g) than NaOH-activated ones (Na-SGM). During the Co(II) adsorption process, these two kinds of geopolymeric adsorbents could be combined with heavy metal ions to optimize each other and form heavy metal-grown aid adsorbents. The morphology of Na-SGM and K-SGM was different which varied from coarse pores to nanonetwork or nanosheets after Co(II) adsorption, and the Brunauer–Emmett–Teller (BET) surface areas of Na-SGM (10.46 m~(2)/g) and K-SGM (22.96 m~(2)/g) increased to 117.38 and 228.73 m~(2)/g after Co(II) adsorption, respectively. The BET surface area of K-SGM is twice that of Na-SGM whether before or after Co(II) ion adsorption. The hydrated ionic radius of K and Na, the alkalinity degree of K~(+) and Na~(+), the electronegativity of Na-SGM and K-SGM surface, the BET surface area and Fourier transform infrared changes of CO_(3)~(2–) and OH before and after Co(II) adsorption, and X-ray photoelectron spectroscopy analysis like the relative content of geopolymer gel and bridging oxygen bonds in the Na-SGM and K-SGM are the fundamental reasons for the obvious differences in Co(II) adsorption between Na-SGM and K-SGM.