Methylene Blue Catalytic Degradation Using Silver and Magnetite Nanoparticles Functionalized with a Poly(ionic liquid) Based on Quaternized Dialkylethanolamine with 2-Acrylamido-2-methylpropane Sulfonate-co-Vinylpyrrolidone

摘要

Catalytic degradation of organic water pollutants has emerged as a cost- and energy-effective technique to treat wastewater. In this work, new silver and magnetite nanoparticles (NPs) were prepared with a protic poly(ionic liquid) (PIL) based on a quaternized diethylethanolamine cation combined with 2-acrylamido-2-methylpropane sulfonate-co -vinylpyrrolidone (QAMPSA/VP) as a capping and a reducing agent. The morphology, particle size, surface charge, thermal stability, and magnetic properties of QAMPS/VP-Ag and Fe_(3)O_(4) NPs were investigated to determine the efficiency of the PIL as a reducing and a capping agent to protect the produced NPs from oxidation or thermal degradation. The activation energy, enthalpy, and entropy of the catalytic degradation of the cationic methylene blue (MB) dye in the presence of QAMPS/VP-Ag and Fe_(3)O_(4) NPs were determined. The data elucidated that MB was completely degraded in 8 min in the presence of QAMPS/VP-Fe_(3)O_(4) NPs as a Fenton oxidation catalyst. Moreover, their good magnetic properties allowed their easy separation and reuse for five cycles without losing their magnetic or catalytic properties.