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Metamaterial emitter for thermophotovoltaics stable up to 1400?°C

机译:用于高温光伏的超材料发射器,稳定在1400?C

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摘要

High temperature stable selective emitters can significantly increase efficiency and radiative power in thermophotovoltaic (TPV) systems. However, optical properties of structured emitters reported so far degrade at temperatures approaching 1200?°C due to various degradation mechanisms. We have realized a 1D structured emitter based on a sputtered W-HfOsub2/sub layered metamaterial and demonstrated desired band edge spectral properties at 1400?°C. To the best of our knowledge the temperature of 1400?°C is the highest reported for a structured emitter, so far. The spatial confinement and absence of edges stabilizes the W-HfOsub2/sub multilayer system to temperatures unprecedented for other nanoscaled W-structures. Only when this confinement is broken W starts to show the well-known self-diffusion behavior transforming to spherical shaped W-islands. We further show that the oxidation of W by atmospheric oxygen could be prevented by reducing the vacuum pressure below 10sup-5/sup?mbar. When oxidation is mitigated we observe that the 20?nm spatially confined W films survive temperatures up to 1400?°C. The demonstrated thermal stability is limited by grain growth in HfOsub2/sub, which leads to a rupture of the W-layers, thus, to a degradation of the multilayer system at 1450?°C.
机译:高温稳定的选择性发射器可以显着提高热光电(TPV)系统的效率和辐射功率。但是,到目前为止,由于各种降解机理,据报道结构化发射体的光学性能在接近1200?C的温度下会下降。我们已经实现了基于溅射的W-HfO 2 层状超材料的一维结构发射体,并展示了在1400°C下所需的能带边缘光谱特性。据我们所知,迄今为止,结构化发射器的最高温度为1400°C。空间限制和边缘的缺乏将W-HfO 2 多层系统稳定在其他纳米级W结构所无法达到的温度下。仅当该限制被打破时,W才开始显示出众所周知的自扩散行为,从而转变为球形W岛。我们进一步表明,通过将真空压力降低到10 -5 mbar可以防止W被大气中的氧气氧化。当减轻氧化作用时,我们观察到20?nm的空间受限的W膜可以在高达1400?C的温度下生存。所证明的热稳定性受到HfO 2 中晶粒生长的限制,这会导致W层的破裂,从而导致多层体系在1450?C的温度下降。

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