Characterizing and Exploring the Formation Mechanism of Salt Deposition by Reusing Advanced-softened, Silica-rich, Oilfield-produced Water (ASOW) in Superheated Steam Pipeline

摘要

To dispose of large volumes of oilfield-produced water, an environmentally friendly method that reuses advanced-softened, silica-rich, oilfield-produced water (ASOW) as feedwater was implemented via a 10-month pilot-scale test in oilfield. However, salt deposition detrimental to the efficiency and security of steam injection system was generated in superheated steam pipeline. To evaluate the method, the characteristics and formation mechanism of the deposition were explored. The silicon content and total hardness of the ASOW were 272.20?mg/L and 0.018?mg/L, respectively. Morphology and composition of the deposition were determined by scanning electron microscope – energy dispersive spectrometry (SEM-EDS), inductively coupled plasma – mass spectroscopy (ICP-MS), X-ray diffraction (XRD), laser Raman spectroscopy (LRS) and X-ray photoelectron spectroscopy (XPS). Na₂Si₂O₅, Na₂CO₃ and trace silanes were identified in the deposition. In addition, the solubility of the deposition was about 99%, suggesting that it is very different from traditional scaling. The results of a simulation experiment and thermal analysis system (TGA and TG-FTIR) proved that Na₂CO₃ and Si(OH)₄ (gas) are involved in the formation of Na₂Si₂O₅, which is ascribed mainly to the temperature difference between the superheated steam and the pipe wall. These findings provide an important reference for improving the reuse of ASOW and reducing its deposition.