We present the results of quantum calculations based on entirely ab initio methods for a variety of molecular processes and chemical reactions involving the LiHe+ ionic polar molecule. With the aid of these calculations, we derive accurate reaction rates and fitting expressions valid over a range of gas temperatures representative of the typical conditions of the pregalactic gas. With the help of a full chemical network, we then compute the evolution of the abundance of LiHe+ as function of redshift in the early universe. Finally, we compare the relative abundance of LiHe+ with that of other polar cations formed in the same redshift interval.
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