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Dimethyl Ether: Laboratory Assignments and Predictions through 600 GHz

机译:二甲醚:通过600 GHz进行的实验室分配和预测

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Dimethyl ether (CH3OCH3) is a well-known interstellar molecule with a large abundance in hot core regions. We have measured many rotational-torsional transition lines of this molecule in the 100-550 GHz frequency range using two experimental techniques: a klystron-based traditional millimeter-wave spectrometer and a new fast scan spectrometer (designated "FASSST") with a voltage-tunable backward wave oscillator. The lines arising from the ground vibrational state have been combined with previous data, mainly at lower frequencies, to form a global data set consisting of over 1600 lines that have been assigned and fitted by an effective Hamiltonian method. The spectral constants obtained from the fit allow us to predict the frequencies of almost 6000 additional lines of dimethyl ether through 600 GHz.
机译:二甲醚(CH3OCH3)是一种众所周知的星际分子,在热核区中的丰度很高。我们已经使用两种实验技术在100-550 GHz频率范围内测量了该分子的许多旋转-扭转跃迁线:基于速调管的传统毫米波光谱仪和新型的快速扫描光谱仪(称为“ FASSST”),其电压为可调反向波振荡器。由地面振动状态产生的线已与以前的数据(主要是在较低的频率)组合在一起,以形成一个由1600多个线组成的全局数据集,这些线已通过有效的汉密尔顿方法进行分配和拟合。从拟合中获得的频谱常数使我们能够预测600 GHz左右的另外6000条二甲醚谱线的频率。

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