Degradation of Phosphate Ester Hydraulic Fluid in Power Station Turbines Investigated by a Three-Magnet Unilateral Magnet Array

摘要

A three-magnet array unilateral NMR sensor with a homogeneous sensitive spot was employed for assessing aging of the turbine oils used in two different power stations. The Carr-Purcell-Meiboom-Gill (CPMG) sequence and Inversion Recovery-prepared CPMG were employed for measuring the 1H-NMR transverse and longitudinal relaxation times of turbine oils with different service status. Two signal components with different lifetimes were obtained by processing the transverse relaxation curves with a numeric program based on the Inverse Laplace Transformation. The long lifetime components of the transverse relaxation time T_2eff and longitudinal relaxation time T₁ were chosen to monitor the hydraulic fluid aging. The results demonstrate that an increase of the service time of the turbine oils clearly results in a decrease of T_2eff,long and T_1,long. This indicates that the T_2eff,long and T_1,long relaxation times, obtained from the unilateral magnetic resonance measurements, can be applied as indices for degradation of the hydraulic fluid in power station turbines.