Electrochemical Performance of a Carbon Nanotube/La-Doped TiO₂ Nanocomposite and its Use for Preparation of an Electrochemical Nicotinic Acid Sensor

摘要

A carbon nanotube/La-doped TiO₂ (La-TiO₂) nanocomposite (CLTN) was prepared by a procedure similar to a complex/adsorption process. Scanning electron microscopy (SEM) images show that the La-TiO₂ distributes on the carbon nanotube walls. The CLTN was mixed with paraffin to form a CLTN paste for the CLTN paste electrode (CLTNPE). The electrochemical characteristics of CLTNPE were compared with that of conventional carbon electrodes such as the carbon paste electrode (CPE) and glass carbon electrode (GC). The CLTNPE exhibits electrochemical activity and was used to investigate the electrochemistry of nicotinic acid (NA). The modified electrode has a strong electro-catalytic effect on the redox of NA. The cyclic voltammetry (CV) redox potential of NA at the CLTNPE is 320 mV. The oxidation process of NA on the CLTNPE is pH dependent. A sensitive chronoamperometric response for NA was obtained covering a linear range from 1.0×10-6 mol·L-1 to 1.2×10-4 mol·L-1, with a detection limit of 2.7×10-7 mol·L-1. The NA sensor displays a remarkable sensitivity and stability. The mean recovery of NA in the human urine is 101.8%, with a mean variation coefficient (RSD) of 2.6%.