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Synthesis of ternary oxide Zn2GeO4 nanowire networks and their deep ultraviolet detection properties

机译:三元氧化物Zn2GeO4纳米线网络的合成及其深紫外检测特性

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Ternary oxide Zn _(2) GeO _(4) with a wide bandgap of 4.84 eV, as a candidate for fourth generation semiconductors, has attracted a great deal of attention for deep ultraviolet (DUV) photodetector applications, because it is expected to be blind to the UV-A/B band (290–400 nm) and only responsive to the UV-C band (200–290 nm). Here, we report on the synthesis of Zn _(2) GeO _(4) nanowire (NW) networks by lower pressure chemical vapor deposition and investigate their corresponding DUV detection properties. We find that pure Zn _(2) GeO _(4) NWs could be obtained at a growth pressure of 1 kPa. The DUV detection tests reveal that growth pressure exerts a significant effect on DUV detection performance. The Zn _(2) GeO _(4) NW networks produced under 1 kPa show an excellent solar-blind photoresponsivity with fast rise and decay times ( t _(rise) ≈ 0.17 s and t _(decay) ≈ 0.14 s).
机译:宽带隙为4.84 eV的三元氧化物Zn _(2)GeO _(4)作为第四代半导体的候选材料,已被期望用于深紫外(DUV)光电探测器,引起了广泛的关注。对UV-A / B波段(290-400 nm)视而不见,仅对UV-C波段(200-290 nm)响应。在这里,我们报告通过低压化学气相沉积合成Zn _(2)GeO _(4)纳米线(NW)网络,并研究其相应的DUV检测性能。我们发现可以在1 kPa的生长压力下获得纯Zn _(2)GeO _(4)NWs。 DUV检测测试表明,生长压力对DUV检测性能具有重要影响。在1 kPa下产生的Zn _(2)GeO _(4)NW网络显示出优异的日盲光响应性,具有快速的上升和衰减时间(t _(上升)≈0.17 s和t _(衰变)≈0.14 s)。

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