A kinetic model for in situ coking denitrification of heavy oil with high nitrogen content based on starch using a structure-oriented lumping method

摘要

In this study, in situ coking denitrification technology was utilized to simplify the entire process by adding an appropriate quantity of denitrification agents to the delayed-coking tower without any further follow-up denitrification process. The effect of starch as the denitrification agent in the in situ coking denitrification process was studied. The distribution of oil products was characterized by GC of simulated distillation. The results indicated that the nitrogen compounds present in heavy oil transformed to coke via in situ coking conversion by reacting with starch. A molecular-level process model for the coking process was developed. Product distribution on the complex reaction network could be described accurately by the model.