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Room-temperature synthesized SnO2 electron transport layers for efficient perovskite solar cells

机译:用于高效钙钛矿太阳能电池的室温合成SnO2电子传输层

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Tin oxide (SnO _(2) ) is widely used as electron transport layer (ETL) material in perovskite solar cells (PSCs). Numerous synthesis methods for SnO _(2) have been reported, but they all require a proper thermal treatment for the SnO _(2) ETLs. Herein we present a simple method to synthesize SnO _(2) nanoparticles (NPs) at room temperature. By using butyl acetate as a precipitator and a proper UV–Ozone treatment to remove Cl residuals, excellent SnO _(2) ETLs were obtained without any thermal annealing. The highest power conversion efficiency (PCE) of the prepared PSCs was 19.22% for reverse scan (RS) and 18.79% for forward scan (FS). Furthermore, flexible PSCs were fabricated with high PCEs of 15.27%/14.74% (RS/FS). The low energy consuming SnO _(2) ETLs therefore show great promise for the flexible PSCs' commercialization.
机译:氧化锡(SnO _(2))被广泛用作钙钛矿太阳能电池(PSC)中的电子传输层(ETL)材料。已经报道了SnO _(2)的许多合成方法,但是它们都需要对SnO _(2)ETL进行适当的热处理。在这里,我们提出了一种在室温下合成SnO_(2)纳米粒子(NPs)的简单方法。通过使用乙酸丁酯作为沉淀剂和适当的UV-臭氧处理以去除Cl残留物,无需任何热退火即可获得出色的SnO _(2)ETL。所准备的PSC的最高功率转换效率(PCE)对于反向扫描(RS)为19.22%,对于正向扫描(FS)为18.79%。此外,制造的柔性PSC具有15.27%/ 14.74%(RS / FS)的高PCE。因此,低能耗的SnO _(2)ETL对灵活的PSC的商业化展示了巨大的希望。

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