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The synthesis of green fluorescent carbon dots for warm white LEDs

机译:用于暖白光LED的绿色荧光碳点的合成

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摘要

Green fluorescent carbon dots (CDs) were synthesized with pyrogallic acid as carbon source by solvothermal method in N , N -dimethylformamide (DMF). During the formation of the CDs, DMF not only serves as solvent for reaction, but also as nitrogen source to participate in the reaction. At the same time, it promotes the formation of large conjugated sp ~(2) -domain in CDs. The prepared CDs have an average size of 11.9?nm, excitation-independent emission centered at 520 nm and fluorescence quantum yield of 16.8%. For practical applications, warm white light-emitting diodes were fabricated by combining the CDs/ N -[3-(trimethoxysilyl)propyl]ethylenediamine (KH-792) mixture with UV chip, which emitted warm white light with color coordinates of (0.39, 0.47) and a correlated color temperature of 4323 K suitable for indoor lighting.
机译:在N,N-二甲基甲酰胺(DMF)中,通过溶剂热法,以焦没食子酸为碳源合成了绿色荧光碳点(CDs)。在形成CD的过程中,DMF不仅充当反应的溶剂,而且充当参与反应的氮源。同时,它促进CD中大的共轭sp〜(2)-结构域的形成。制备的CD的平均尺寸为11.9?nm,与激发无关的发射中心在520 nm,荧光量子产率为16.8%。对于实际应用,通过将CDs / N-[3- [三(三甲氧基甲硅烷基)丙基]乙二胺(KH-792)混合物与UV芯片结合在一起,制成了暖白色发光二极管,它发出了色坐标为(0.39, 0.47)和相关色温4323 K适用于室内照明。

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