Dynamic Simulation of Petrochemical Wastewater Treatment Using Wastewater Plant Simulation Software

摘要

A dynamic simulation model was developed, calibrated and validated for a petrochemical plant in Terengganu, Malaysia. Calibration and validation of the model was conducted based on plant monitoring data spanning 3 years resulting in a model accuracy (RMSD) for effluent chemical oxygen demand (COD), ammoniacal nitrogen (NH_(3)-N) and total suspended solids (TSS) of ±11.7 mg/L, ±0.52 mg/L and ± 3.27 mg/L respectively. The simulation model has since been used for troubleshooting during plant upsets, planning of plant turnarounds and developing upgrade options. A case study is presented where the simulation model was used to assist in troubleshooting and rectification of a plant upset where ingress of a surfactant compound resulted in high effluent TSS and COD. The model was successfully used in the incident troubleshooting activities and provided critical insights that assisted the plant operators to quickly respond and bring back the system to normal, stable condition.