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Chemical Characterization of Stabilized and Carbonized Polyacrylonitrile (PAN) Fibers Treated with Oleic Acid.

机译:油酸处理的稳定化碳化聚丙烯腈(PAN)纤维的化学表征。

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Polyacrylonitrile (PAN) fiber is the best precursor for carbon fibers due to high carbon content after heat treatment. After the polymer was spun into fibers, the fibers will undergo pretreatment process with chemical solution known as post spinning treatment. Post spinning will directly affect conversion of PAN fiber to carbon fiber. Oleic acid was used as post spinning treatment chemical solution to PAN fibers. The pretreated PAN fiber will be heated at 250°C and 800°C. The fibers were studied using Fourier Transform Infra-Red (FTIR), X-ray Photoelectron Spectroscopy (XPS) and DSC to study the chemical change during heat treatment. PAN fibers treated with oleic acid have reduced the cyclization energy and increase oxygen and carbon content leading to high performance carbon fibers.
机译:聚丙烯腈(PAN)纤维是热处理后碳含量最高的碳纤维的最佳前体。将聚合物纺制成纤维后,纤维将采用化学溶液进行预处理,即后纺丝处理。后纺将直接影响PAN纤维向碳纤维的转化。油酸用作PAN纤维的纺丝后处理化学溶液。预处理的PAN纤维将在250°C和800°C下加热。使用傅里叶变换红外(FTIR),X射线光电子能谱(XPS)和DSC对纤维进行了研究,以研究热处理过程中的化学变化。用油酸处理过的PAN纤维降低了环化能并增加了氧和碳的含量,从而形成了高性能的碳纤维。

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