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Process Optimization for Preparing High Performance PAN-based Carbon Fibers

机译:制备高性能PAN基碳纤维的工艺优化

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Optimum process conditions were investigated for maximizing the mechanical properties of the carbon fiber by from wet spun polyacrylonitrile (PAN) fiber precursors. The process variables chosen were treatment temperature, applied tension in stabilization process. The temperature profile of the stabilization was set on the basis of exothermic peaks of the differential scanning calorimetry (DSC) result. Both tensile strength and modulus increased with holding at onset temperatures of the exothermic peaks for extended duration, and with a higher heating rate up to the onset temperatures at a given applied tension among the experimental conditions. The increase in load monotonously increased the tensile modulus, on the other hand, the tensile strength was maximum at the load of 15 mg/filament (T15). The load 20 mg/ filament (T20) was considered to be exceeded to form oriented crystalline structure, possibly introducing more defects in the fiber than under load of T15. The sample CP3-T15 O5 H30 showed the best tensile properties among the samples experimented whose tensile properties are compatible with the commercialized grade of general purpose carbon fibers even at low carbonization temperature such as 800 oC (the carbonization temperature in the commercial process. 1300…1500 oC).
机译:研究了通过湿纺聚丙烯腈(PAN)纤维前体最大化碳纤维机械性能的最佳工艺条件。选择的过程变量是处理温度,稳定过程中施加的张力。稳定温度曲线是根据差示扫描量热法(DSC)结果的放热峰设定的。拉伸强度和模量都随着放热峰的起始温度保持较长时间而增加,并且在实验条件下,在给定的施加张力下,达到起始温度的升温速率更高。载荷的增加单调地提高了拉伸模量,另一方面,在15mg /丝的载荷(T15)下,拉伸强度最大。认为超过了20 mg /丝(T20)的负载以形成定向的晶体结构,与在T15的负载下相比,可能在光纤中引入了更多的缺陷。 CP3-T15 O5 H30样品显示出最佳的拉伸性能,即使在较低的碳化温度(例如800 oC(商业化过程中的碳化温度)下,其拉伸性能也与商品级通用碳纤维兼容)。 1500 oC)。

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