Simulation of the Solution EPR Spectra of Mixed-Valence Heteropolyanions Containing Vanadium(￥3) and Vanadium(￥′)

Chul Wee Lee; Duckhwan Lee; Hyunsoo So

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Simulation of the Solution EPR Spectra of Mixed-Valence Heteropolyanions Containing Vanadium(￥3) and Vanadium(￥′)

机译：含钒（￥ 3）和钒（￥′）的混合价杂多阴离子溶液EPR谱的模拟

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Modified Bloch equations were used to simulate the solution EPR spectra of mixed-valence heteropolyanions containing vanadium(コ) and vanadium(ゴ). Simulated are the 15-, 22-, 36- and 43-line spectra of メ-1,2-[PV(コ)VW10)O40]6-, [P2V(コ) V2W15O62]10-, [HP2V(コ)V2W15O62]9- and メ-1,2,3-[HSiV(コ)V2W9O40]7-, respectively. The transition probabilities for the intramolecular electron transfer were determined from the simulations.

机译：修改后的Bloch方程用于模拟含钒和钒的混合价杂多阴离子的溶液EPR光谱。模拟的是メ-1,2- [PV（コ）VW10）O40] 6-，[P2V（コ）V2W15O62] 10-，[HP2V（コ）的15、22、36和43线光谱V2W15O62] 9-和メ-1,2,3- [HSiV（コ）V2W9O40] 7-。从模拟确定分子内电子转移的跃迁概率。

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《Bulletin of the Korean Chemical Society》 |1987年第5期|共页
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Chul Wee Lee; Duckhwan Lee; Hyunsoo So;
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中图分类化学;
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Simulation of the Solution EPR Spectra of Mixed-Valence Heteropolyanions Containing Vanadium(￥3) and Vanadium(￥′)

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