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首页> 外文期刊>Journal of the Korean Chemical Society >Studies of Purifying Waste Cotton for Esterification & Molecular Weight Distribution Curve of Cellulose Acetate
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Studies of Purifying Waste Cotton for Esterification & Molecular Weight Distribution Curve of Cellulose Acetate

机译:废棉酯化纯化及醋酸纤维素分子量分布曲线的研究。

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摘要

Purified cellulosic materials suitable for the production of cellulose esters can be prepared from waste cotton (carding waste from textile mill). The most desirable conditions in purifying waste cotton were obtained. Waxy materials were removed by boiling in 2-3%, soda ash solution for more than 30 minutes in open vessel at atmospheric pressure. As for bleaching, it is desirable to use the bleaching powder solution containing l%, available chlorine for 60 minutes at 35 deg. C. Purified cellulosic material was acetylated to fibrous cellulose triacetate, which was fractionated in the solution of 70% monochloroacetic acid using water as a precipitant, and the degree of polymerizaion and molecular weight of each fraction were measured viscometrically, thereon, molecular weight distribution curve was drawn. Analyzing the shape of this curve, most of the polymers were concentrated on the part of higher degree of polymerization. Purified waste cotton was also analysed, the result was that this cellulosic material can be used as a raw material for cellulose esters and ethers.
机译:适用于生产纤维素酯的纯化纤维素材料可以由废棉(纺织厂的梳棉废料)制备。获得了净化废棉的最理想条件。在大气压下于敞口容器中于2-3%的纯碱溶液中煮沸30分钟以上,即可除去蜡状物质。至于漂白,理想的是在35℃下使用含有1%有效氯的漂白粉溶液60分钟。 C.将纯化的纤维素材料乙酰化为纤维状三乙酸纤维素,将其在70%一氯乙酸溶液中以水为沉淀剂进行分馏,并通过粘度法测量各部分的聚合度和分子量,在其上,分子量分布曲线被画。分析该曲线的形状,大多数聚合物集中在较高聚合度的部分。还分析了纯化的废棉,结果是该纤维素材料可用作纤维素酯和醚的原料。

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