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LONG-TERM PHYSICAL AGEING IN VITREOUS ARSENIC SELENIDES

机译:玻璃体砷化物的长期物理老化

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Effects of long-term physical aging ($sim $20 years) studied in vitreous arsenic selenides using differential scanning calorimetry are compared with conventional short-term physical aging (up to 1 year). It is shown that these effects differ not only by their amplitudes (increase in glass transition temperature and endothermic peak area near the glass transition), but also by compositional dependences. These results clearly testify in a favour of a sufficient difference in microstructural origin for short- and long-term physical aging in chalcogenide glasses.
机译:使用差示扫描量热法研究了玻璃化硒化砷中的长期物理老化($ sim $ 20年)的影响,并将其与常规的短期物理老化(长达1年)进行了比较。结果表明,这些效应不仅因其幅度(玻璃化转变温度的升高和玻璃化转变附近的吸热峰面积的增加)而不同,而且还随成分的不同而不同。这些结果清楚地证明,硫属化物玻璃的微观结构来源有足够的差异,可以实现短期和长期的物理老化。

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