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EXCITON SPECTRA OF THE NANOSTRUCTURED ZINC OXIDE

机译:纳米结构氧化锌的激子谱

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A simple two-step approach to produce ZnO nanorods and nanotubes by electron sputtering of the metallic zinc in vacuum and then oxidizing it to ZnO in air is reported. It has been found that the samples synthesised by this method exhibited much more intense exciton photoluminescence around $sim$370 nm in comparison with the usual flat zinc oxide thin films. The clearly distinguished bands corresponding to localised exciton states and phonon replicas testify to quite high crystallinity of the obtained nanorods (nanotubes). The slight but noticeable blueshift (4 meV) in the near band edge luminescence for the sample with nanotubes in comparison with the samples with nanorods and flat films could reflect the quantum confinement effect.
机译:报道了一种简单的两步法,该方法通过在真空中电子溅射金属锌然后在空气中将其氧化为ZnO来生产ZnO纳米棒和纳米管。已经发现,与通常的平坦氧化锌薄膜相比,通过这种方法合成的样品在$ sim $ 370 nm附近表现出更强的激子光致发光。与局部激子态和声子复制体相对应的清晰区分的条带证明了所获得的纳米棒(纳米管)的结晶度很高。与具有纳米棒和平坦膜的样品相比,具有纳米管的样品的近带边缘发光中的轻微但明显的蓝移(4meV)可以反映量子限制效应。

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