Reconstruction of pH in the Surface Seawater over the North Pacific Basin for All Seasons Using Temperature and Chlorophyll-a

摘要

We found a simple function of pH that relates to sea surface temperature (SST, K) and chlorophyll-a (Chl, μg l?1) using measured surface seawater pH, SST and Chl data sets over the North Pacific: pH (total hydrogen scale at 2°C) = 0.01325 SST ? 0.0253 Chl + 4.150 (R2 = 0.95, p < 0.0001, n = 483). Moreover, evaluating the seasonal variation of pH based on this algorithm, we compared the measured pH with the predicted pH at the observational time series stations in subpolar and subtropical regions. The average of ΔpH (measured - predicted, n = 52) was 0.006 ± 0.022 pH. Therefore, the combination of SST and Chl can allow us to determine the spatiotemporal distribution of pH over the North Pacific. Using the climatological data sets of SST and Chl with our pH algorithms, we have described the seasonal distributions of pH at 25°C (pH(25)) and pH in situ temperature (pH(T)) over the North Pacific surface water.