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Microwave-assisted synthesis of silver nanoparticles and their application in catalytic, antibacterial and antioxidant activities

机译:微波辅助合成银纳米粒子及其在催化,抗菌和抗氧化活性中的应用

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Eco-friendly silver nanoparticles (AgNPs) were synthesized using a carboxymethylated gum kondagogu (CMGK) as capping and reducing agent by microwave irradiation method. Synthesized AgNPs were analyzed by TEM, showed spherical in shape with an average particle size distribution of 9?±?2?nm. XRD results showed that the cubic-structured AgNPs with crystallite size of 8.6?nm. The synthesized CMGK capped AgNPs was tested for catalytic activity using hexacyanoferrate(III) in the presence of NaBH~(4)and the impacts of catalyst dose and temperature were examined. The synthesized AgNPs demonstrated a huge antibacterial action on both Gram-positive and negative groups of microorganisms with inhibition zone of 23, 25 and 28?mm, respectively, for Bacillus subtilis , Bacillus cereus and Escherichia coli , they showed moderate antibacterial action (zone of inhibition 15?mm) with Pseudomonas aeruginosa. In addition, the ability of the AgNPs scavenging activity with different concentrations was studied using the DPPH radical scavenging.
机译:以羧甲基化的口香糖(CMGK)为加帽和还原剂,通过微波辐射法合成了环保银纳米颗粒(AgNPs)。合成的AgNP通过TEM分析,呈球形,平均粒径分布为9≤±2≤2nm。 XRD结果表明,立方结构的AgNPs的晶粒尺寸为8.6?nm。在NaBH〜(4)存在下,使用六氰合铁酸酯(III)测试了合成的CMGK封端的AgNPs的催化活性,并考察了催化剂用量和温度的影响。合成的AgNPs对枯草芽孢杆菌,蜡状芽孢杆菌和大肠杆菌的抑菌区分别为23、25和28?mm,对革兰氏阳性和阴性菌均显示出巨大的抗菌作用,它们显示出中等的抗菌作用(抑制15?mm)与铜绿假单胞菌。另外,使用DPPH自由基清除剂研究了不同浓度的AgNP清除能力。

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