Study of solid state interactions in the systems ZnFe2O4 - CaO, ZnFe2O4 - MgO and zinc cake with CaO and MgO

Peltekov A.B.; Boyanov B.S.

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Study of solid state interactions in the systems ZnFe2O4 - CaO, ZnFe2O4 - MgO and zinc cake with CaO and MgO

机译：ZnFe2O4-CaO，ZnFe2O4-MgO和锌饼与CaO和MgO的固相相互作用的研究

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The solid state interactions of CaO and MgO with synthetic and industrial ZnFe2O4 (in zinc cake) have been studied using chemical, XRD analysis and M?ssbauer spectroscopy. The exchange reactions in the systems ZnFe2O4 - CaO and ZnFe2O4 - MgO have been investigated in the range of 850-1200oC and duration up to 180 min. It has been established that Ca2+ and Mg2+ ions exchange Zn2+ in ferrite partially and the solubility of zinc in a 7% sulfuric acid solution increases. The possibilities for utilization of the obtained results in zinc hydrometallurgy have been discussed.

机译：使用化学，XRD分析和Msssbauer光谱研究了CaO和MgO与合成的和工业的ZnFe2O4（在锌饼中）的固态相互作用。 ZnFe2O4-CaO和ZnFe2O4-MgO系统中的交换反应已在850-1200oC的温度范围内进行了研究，持续时间长达180分钟。已经确定Ca 2+和Mg 2+离子在铁素体中部分交换Zn 2+，并且锌在7％硫酸溶液中的溶解度增加。讨论了在锌湿法冶金中利用所得结果的可能性。

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《Journal of Mining and Metallurgy, Section B: Metallurgy》 |2013年第3期|共8页
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Peltekov A.B.; Boyanov B.S.;
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7. Study of solid state interactions in the systems ZnFe2O4 - CaO, ZnFe2O4 - MgO and zinc cake with CaO and MgO [O] . Peltekov A.B., Boyanov B.S. 2013

机译：含CaO和mgO的ZnFe2O4 - CaO，ZnFe2O4 - mgO和锌饼系固态相互作用的研究

Study of solid state interactions in the systems ZnFe2O4 - CaO, ZnFe2O4 - MgO and zinc cake with CaO and MgO

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