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Pretreating Stored Human Urine for Solar Evaporation by Low-Technology Ammonia Stripping

机译:低技术氨汽提法预处理储存的人类尿液以进行太阳蒸发

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In order to avoid the loss of ammonia during solar drying of stored urine, low-tech stripping is suggested as a pretreatment process for ammonia recovery. The mass transfer of ammonia from stored urine with an initial pH of about 9 was tested in a simple closed vessel operated at 72°C, 74°C and 85°C. The specific urine/gas interface was 16.97 m-1. For ammonia absorption, a beaker with sulfuric acid was positioned in the gas phase of the container. After keeping the stored urine for 73 h at 85°C, the concentration of free ammonia (NH3) was reduced by more than 99%, and the pH of the stored urine decreased to 6.4 due to ammonia volatilization. Total ammonia (NH3+ NH4+) concentration was reduced by only 83% in the same period. At lower temperatures, the process was slower. Required treatment time can be reduced when specific gas/liquid interface is increased. Because it is known that water can be heated in solar boxes to temperatures above 90°C, this simple stripping apparatus is feasible to be operated with solar energy in remote areas with suitable climatic conditions where no electric power is available. As the area demand for solar “low-tech stripping” is less than 1 m2 per capita, this process can be looked at as a suitable pretreatment of stored urine prior to solar evaporation.
机译:为了避免在储存的尿液经过太阳能干燥过程中氨气的损失,建议使用低技术汽提法作为氨气回收的预处理方法。在72°C,74°C和85°C的简单密闭容器中测试了初始pH约为9的氨从储存尿液中的传质。特定的尿/气界面为16.97 m-1。为了吸收氨,将带有硫酸的烧杯放置在容器的气相中。将储存的尿液在85°C下放置73小时后,游离氨(NH3)的浓度降低了99%以上,并且由于氨气挥发,储存的尿液的pH值降至6.4。在同一时期,总氨(NH3 + NH4 +)的浓度仅降低了83%。在较低温度下,该过程较慢。当增加特定的气/液界面时,可以减少所需的处理时间。因为已知可以在太阳能箱中将水加热到90°C以上的温度,所以这种简单的汽提设备在具有合适气候条件且没有电力可用的偏远地区用太阳能操作是可行的。由于太阳能“低技术剥离”的人均需求量不足1平方米,因此该过程可以看作是在太阳能蒸发之前对储存的尿液进行的合适预处理。

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