Coiled Fibers of Poly (Amide-Co-Imide) PAI and Poly (Trimellitic Anhydride Chloride-Co-4, 4’-MethyleneDianiline) (PTACM) By Using Mechano-Electrospinning

摘要

Non-linear coil shaped uniform fibers were synthesized with the blend solution of Poly (amide-coimide) PAI (torlon)/Poly (trimellitic anhydride chloride-co-4, 4’-methylene dianiline) (PTACM) in solvent mixing ratio of DMSO and THF (6:4) by using mechano-electrospinning. The linear shape and decrease in size of fiber was observed as the concentration of blend solution decreases from 30-27 %. However if concentration was reduced to 26 %, regular coil shaped uniform fibers were produced. We also found that solution prepared in 6:4 (DMSO/THF) and concentration less than 26 % did not facilitate continuous electrospinning. The properties of these blends were investigated using a rotational rheometer and SEM, in an attempt to understand the relationships between their rheological and morphological properties. It was concluded that concentration of solution played an important role to the diameter of fiber and significant impact on the shape of fiber.