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Design and characterization of novel conductive nanocomposites based on carbon nanotube modified liquid crystalline epoxy

机译:基于碳纳米管改性液晶环氧树脂的新型导电纳米复合材料的设计与表征

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摘要

In this work, a series of novel isotropically conductive adhesives (ICAs) based on multiwalled carbon nanotube (MWCNT)-modified liquid crystalline epoxy (LCE) resin was prepared. Different loadings of MWCNTs were used to produce LCE composites. Transmission electron microscope, scanning electron microscope, differential scanning calorimetry, polarized light optical microscopy, X-ray diffraction, electrical conductivity measurement, and tensile and flexural measurements were used to characterize the morphology, thermal, phase change, electrical, and mechanical properties of the prepared composites. The results showed that the added MWCNTs were dispersed well in the LCE matrix. The introducing MWCNTs did not show any major influence on typical curing peaks of LCE. Electrical conductivity at room temperature of the composites was increased significantly compared with neat LCE. The conductivity value of 10~(?2)?S?cm~(?1) was obtained at a weight concentration of only 0.5% MWCNT. In addition, tensile strength, Young’s modulus, flexural strength, and flexural modulus of the composites were increased clearly compared with neat LCE matrix. These produced LCE composites with very low MWCNT loadings showed a great prospect of being used as ICAs.
机译:在这项工作中,准备了一系列基于多壁碳纳米管(MWCNT)改性液晶环氧树脂(LCE)树脂的新型各向同性导电胶(ICAs)。不同负载的MWCNT用于生产LCE复合材料。透射电子显微镜,扫描电子显微镜,差示扫描量热法,偏光光学显微镜,X射线衍射,电导率测量以及拉伸和挠曲测量被用来表征合金的形态,热,相变,电学和机械性能。准备好的复合材料。结果表明,添加的MWCNTs在LCE基质中分散良好。引入的MWCNT对LCE的典型固化峰没有显示出任何主要影响。与纯LCE相比,复合材料在室温下的电导率显着提高。在重量浓度仅为0.5%MWCNT的情况下,电导率为10〜(?2)?S?cm?(?1)。此外,与纯LCE基质相比,复合材料的拉伸强度,杨氏模量,弯曲强度和弯曲模量明显增加。这些生产的极低MWCNT含量的LCE复合材料显示出用作ICA的广阔前景。

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