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Semi-interpenetrating network composites reinforced with Kevlar fibers for dental post fabrication

机译:牙科后加工用芳纶纤维增强的半互穿网络复合材料

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摘要

This study evaluates the reinforcement of semi-interpenetrating network composites of 2,2-bis[4-(2-hydroxy-3-methacryloyloxypropyl)phenyl] propane (Bis-GMA)/ triethyleneglycol dimethacrylate (TEGDMA)/polymethyl methacrylate (PMMA) and 25% titanium dioxide (TiO_(2)) nanofiller with surface treated Kevlar fibers for potential application as dental posts. The post material was subjected to thermo-cycling and flexural strength determined, characterised by dynamic mechanical analysis, water sorption, radiopacity and cytotoxicity tests. The results were compared with everStick~(?)POST. Kevlar pre-treatment with acetic acid and silane coupling agent demonstrated a clear effect on the flexural strength of the composites with a significant increase compared to composites with fibers without surface treatment. The inclusion of TiO_(2) into the final formulation provided the desired radiopacity and improved both aesthetics and flexural strength, which exhibits a higher resistance on thermocycling. The ratios of fatigue limit to static flexural strength were about 0.73 for Kevlar and 0.58 for everStick~(?)POST; MTT assay confirmed the absence of any toxic eluents, indicating its feasibility as new intracanal post material.
机译:本研究评估了2,2-双[4-(2-羟基-3-甲基丙烯酰氧基丙基)苯基]丙烷(Bis-GMA)/三乙二醇二甲基丙烯酸酯(TEGDMA)/聚甲基丙烯酸甲酯(PMMA)的半互穿网络复合材料的增强具有表面处理的凯夫拉纤维的25%二氧化钛(TiO_(2))纳米填料,有可能用作牙桩。通过动态力学分析,吸水率,射线不透性和细胞毒性测试对柱材料进行热循环和弯曲强度测定。将结果与everStick〜(?)POST进行比较。与未进行表面处理的纤维复合材料相比,用乙酸和硅烷偶联剂进行的凯夫拉尔预处理对复合材料的抗弯强度具有明显的影响,并且显着提高。最终配方中包含TiO_(2)可提供所需的不透射线性,并改善美学和抗弯强度,在热循环中表现出更高的抵抗力。疲劳极限与静态挠曲强度的比值对于凯夫拉尔约为0.73,对于everStick〜(?)POST为0.58。 MTT测定法证实不存在任何有毒的洗脱液,表明其作为新的管内桩后材料的可行性。

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