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Kinetic and modeling data on phenol removal by Iron-modified Scoria Powder (FSP) from aqueous solutions

机译:铁改性Scoria粉末(FSP)从水溶液中去除苯酚的动力学和模型数据

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Phenol present in industrial effluents is a toxicant matter which causes pollution of environments aqueous. In this work, scoria was modified by iron in order to increasing of adsorbent efficiency and effective removing of phenol. Effects of independent variables including pH, adsorbents dosage, contact time and adsorbate concentration on removing of phenol were studied by response surface methodology (RSM) based on the central composite designs (CCD). The characterization of raw scoria powder (RSP) and Iron-modified Scoria Powder (FSP) was determined via Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), scanning electron microscopy (SEM) and Energy-dispersive X-ray spectroscopy (EDS). The obtained data showed modification by iron caused the growth of new crystalline of iron oxide on the surface of FSP. Evaluated data by RSM indicated the all variables especially pH are effective in removing of phenol (P-value?
机译:工业废水中存在的苯酚是一种有毒物质,会对水性环境造成污染。在这项工作中,氧化铁被铁改性,以提高吸附效率和有效去除苯酚。通过基于中心复合设计(CCD)的响应面方法(RSM)研究了pH,吸附剂用量,接触时间和吸附物浓度等自变量对苯酚去除的影响。通过傅立叶变换红外光谱(FTIR),X射线衍射(XRD),扫描电子显微镜(SEM)和能量色散X射线测定了粗氧化铈粉末(RSP)和铁改性的氧化钴粉末(FSP)的特征光谱学(EDS)。获得的数据表明,铁的改性导致FSP表面上新的氧化铁晶体的生长。 RSM评估的数据表明,所有变量,特别是pH值都能有效地去除苯酚(P值≤0.001),并且在pH≤5,苯酚浓度50毫克/升,吸附剂剂量50时获得了最佳条件。 =1μg/ l,接触时间=100μmin,至94.99%,期望值为0.939。结果表明,数据通过Langmuir等温线(R2 =?0.9938)和伪二级动力学(R2 =?0.9976)拟合。已经发现铁导致增加了熔渣的活性位点并导致苯酚的显着去除。

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