Concentration Dependence of Thermodynamic Properties of NaPb Liquid Alloy

摘要

We have determined integral excess free energy of mixing, heat of mixing and entropy of mixing of NaPb alloys in molten state at 700 K. The observed asymmetry in the properties of mixing of NaPb alloy in molten state is successfully explained on the basis of regular associated solution model. The theoretical analysis reveals that the pairwise interaction energies between the species depend considerably on temperature.