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A Thermodynamical Approach for Evaluating Energy Consumption of the Forward Osmosis Process Using Various Draw Solutes

机译:一种热力学方法,使用各种抽提溶液评估正向渗透过程的能耗

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The forward-osmosis (FO) processes have received much attention in past years as an energy saving desalination process. A typical FO process should inclu de a draw solute recovery step which contributes to the main operation costs of the process. Therefore, investigating the energy consumption is very important for the development and employment of the forward osmosis process. In this work, NH3-CO2, Na2SO4, propylene glycol mono-butyl ether, and dipropylamine were selected as draw solutes. The FO processes of different draw solute recovery approaches were simulated by Aspen PlusTM with a customized FO unit model. The electrolyte Non-Random Two-Liquid (Electrolyte-NRTL) and Universal Quasi Chemical (UNIQUAC) models were employed to calculate the thermodynamic properties of the feed and draw solutions. The simulation results indicated that the FO performance decreased under high feed concentration, while the energy consumption was improved at high draw solution concentration. The FO process using Na2SO4 showed the lowest energy consumption, followed by NH3-CO2, and dipropylamine. The propylene glycol mono-butyl ether process exhibited the highest energy consumption due to its low solubility in water. Finally, in order to compare the equivalent work of the FO processes, the thermal energy requirements were converted to electrical work.
机译:近年来,正向渗透(FO)工艺作为一种节能淡化工艺受到了广泛关注。典型的FO工艺应包括溶质回收步骤,这会增加工艺的主要运营成本。因此,调查能耗对于正渗透过程的发展和应用非常重要。在这项工作中,选择了NH3-CO2,Na2SO4,丙二醇单丁醚和二丙胺作为牵引溶质。 Aspen PlusTM使用定制的FO单元模型模拟了不同抽提溶质回收方法的FO过程。使用电解质非随机二液(Electrolyte-NRTL)和通用拟化学(UNIQUAC)模型来计算进料和汲取溶液的热力学性质。模拟结果表明,在高进料浓度下,FO性能下降,而在高进料溶液浓度下,能量消耗得到改善。使用Na2SO4的FO工艺显示出最低的能耗,其次是NH3-CO2和二丙胺。丙二醇单丁醚工艺由于在水中的溶解度低而显示出最高的能耗。最后,为了比较FO过程的等效功,将热能需求转换为电功。

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