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首页> 外文期刊>The Open Structural Biology Journal >Structures of the Molecular Components in DNA and RNA with Bond Lengths Interpreted as Sums of Atomic Covalent Radii
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Structures of the Molecular Components in DNA and RNA with Bond Lengths Interpreted as Sums of Atomic Covalent Radii

机译:结合长度解释为原子共价半径之和的DNA和RNA分子组成的结构

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摘要

The author has found recently that the lengths of chemical bonds are sums of the covalent and or ionic radii ofthe relevant atoms constituting the bonds, whether they are completely or partially covalent or ionic. This finding has beentested here for the skeletal bond lengths in the molecular constituents of nucleic acids, adenine, thymine, guanine, cytosine,uracil, ribose, deoxyribose and phosphoric acid. On collecting the existing data and comparing them graphically withthe sums of the appropriate covalent radii of C, N, O, H and P, it is found that there is a linear dependence with effectivelyunit slope and zero intercept. This shows that the bond lengths in the above molecules can be interpreted as sums of therelevant atomic covalent radii. Based on this result, the author has presented here the atomic structures of the above moleculesin terms of the atomic radii (for the first time).
机译:作者最近发现,化学键的长度是构成键的相关原子的共价和/或离子半径之和,无论它们是完全或部分共价还是离子。在此测试了该发现的核酸,腺嘌呤,胸腺嘧啶,鸟嘌呤,胞嘧啶,尿嘧啶,核糖,脱氧核糖和磷酸的分子成分中的骨架键长。在收集现有数据并将其与C,N,O,H和P的适当共价半径之和进行图形比较后,发现存在线性相关性,有效单位斜率和零截距。这表明上述分子中的键长可以解释为相关原子共价半径的总和。基于这个结果,作者在这里以原子半径(首次)展示了上述分子的原子结构。

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