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Corrosion Behavior of 3% Cr Casing Steel in CO2-Containing Environment: A Case Study

机译:含CO 2的环境中3%Cr套管钢的腐蚀行为:一个案例研究

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Introduction:The production casing of 3% Cr steel has encountered severe internal corrosion in Huizhou Oilfield. To disclose corrosion behavior of inner casing, a series of corrosion exposure tests were systematically conducted on 3% Cr coupons in terms of in-field conditions.Material and Methods:Influence of exposure time, temperature, and water-cut on the CO2 corrosion of 3% Cr steel was investigated, and analyses on weight loss, composition and morphology of corrosion product, and Tafel polarization curves were further carried out.Result: The results showed that the corrosion rate of 3% Cr steel increased with increasing temperature, but such trend descended when the temperature exceeded 65°C due to formation of an compact and adherent corrosion product film on the surface of 3% Cr coupons. While varying exposure time from 7 days to 14 days, the corrosion rate decreased, and the Cr and O enrichment was determined in the corrosion products. The corrosion rate of 3% Cr steel increased with a continuous increment of water-cuts, especially when the water-cut was larger than 40%.Conclusion:The localized corrosion can happen at the lower water-cut due to the presence of amorphous films. The main corrosion products were FeCO3, Cr5O12, Fe2O3, and Fe-Cr. Entry of CO2 to the simulated formation water caused an increase in the anodic Tafel slope, and accelerated dissolution of 3% Cr steel.
机译:简介:3%Cr钢的生产套管在惠州油田遇到严重的内部腐蚀。为了揭示内壳的腐蚀行为,在野外条件下,系统地对3%Cr试样进行了一系列腐蚀暴露测试。材料与方法:暴露时间,温度和含水率对CO2腐蚀的影响对3%Cr钢进行了研究,并对失重,腐蚀产物的组成和形貌以及Tafel极化曲线进行了分析。结果:结果表明,3%Cr钢的腐蚀速率随温度的升高而增加,但是当温度超过65°C时,由于在3%Cr试样表面上形成致密且粘附的腐蚀产物膜,这种趋势下降。当暴露时间从7天更改为14天时,腐蚀速率降低,并且确定了腐蚀产物中的Cr和O富集。 3%Cr钢的腐蚀速率随着含水率的不断增加而增加,特别是当含水率大于40%时结论。结论:由于非晶膜的存在,较低含水率会发生局部腐蚀。主要腐蚀产物为FeCO3,Cr5O12,Fe2O3和Fe-Cr。 CO2进入模拟地层水中导致阳极Tafel斜率增加,并加速了3%Cr钢的溶解。

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