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Extraction of Clove and Vetiver Oils with Supercritical Carbon Dioxide: Modeling and Simulation

机译:超临界二氧化碳萃取丁香和香根草油:建模和模拟

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The kinetics of supercritical fluid extraction (SFE) of clove and vetiver oils using carbon dioxide as solvent wasstudied, in order to establish an efficient method to predict extraction curves on large scale. The mass transfer model ofSovová was used to adjust the experimental SFE data, which were obtained at 100 bar and 35 °C for clove and 200 barand 40 °C for vetiver, using extraction columns of different geometry and solvent flow rates. Some other process parameters,such as bed density and porosity, solvent to feed ratio and solvent velocity were kept constant from one experimentto another, in order to verify if the mass transfer coefficients adjusted by the model varied. The results show that themodel of Sovová was able to predict an overall extraction curve for clove from data obtained with twenty times less rawmaterial, since the mass transfer coefficients remained the same and the predicted curves were similar to the observedones. For vetiver, the simulation was not as effective, probably due to the effects of transport properties on the process.
机译:研究了以二氧化碳为溶剂的丁香和香根草油的超临界流体萃取动力学,从而建立了预测大规模萃取曲线的有效方法。使用Sovová的传质模型来调整实验SFE数据,该数据是使用不同几何形状和溶剂流速的萃取柱在100 bar和35°C的丁香和200 barand 40°C的香根草获得的。从一个实验到另一个实验,使床密度和孔隙率,溶剂进料比和溶剂速度等其他过程参数保持恒定,以验证模型调整的传质系数是否变化。结果表明,由于传质系数保持不变并且预测的曲线与观察到的相似,因此,Sovová模型能够从使用少20倍的原料获得的数据中预测丁香的总体提取曲线。对于香根草而言,模拟效果不佳,可能是由于运输特性对工艺的影响。

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