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Simulation and sensitivity analysis for biodiesel production in a reactive distillation column

机译:反应蒸馏塔中生物柴油生产的模拟和灵敏度分析

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The conventional process for biodiesel production by transesterification is still expensive due to a need of high excess of alcohol required and its recovery by distillation. The use of a reactive distillation process can reduce the amount of alcohol in the feed stream as it works on a simultaneous reaction and separation. In the present study, a mathematical model has been developed for biodiesel production from triglycerides in a reactive distillation column, which has been validated with the reported data and CHEMCAD results. The effects of process parameters such as methanol to oil feed ratio, feed temperature, and reaction time have been investigated. The sensitivity analysis shows that yield of ester increases with methanol to oil ratio and number of stages, however, it decreases with fl ow rate. The MATLAB simulated results show that methanol to oil molar ratio of 5:1 produces 90% (by wt.) of methyl ester in a residence time of 4.7 minutes.
机译:通过酯交换反应生产生物柴油的常规方法仍然昂贵,这是因为需要大量过量的醇及其通过蒸馏回收的方法。反应性蒸馏方法的使用可以减少进料流中的醇量,因为它可以同时进行反应和分离。在本研究中,已经开发了用于在反应蒸馏塔中由甘油三酸酯生产生物柴油的数学模型,该模型已通过报告的数据和CHEMCAD结果进行了验证。研究了工艺参数如甲醇与油的进料比,进料温度和反应时间的影响。敏感性分析表明,酯收率随甲醇/油比和级数的增加而增加,但随流率的降低而降低。 MATLAB仿真结果表明,甲醇与油的摩尔比为5:1,在4.7分钟的停留时间内可生成90%(重量)的甲酯。

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