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Chromium in Anthropogenically Polluted and Naturally Enriched Soils: A Review

机译:人为污染和自然富裕土壤中的铬:综述

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Chromium (Cr) is a very important element examined for last decades on many expert fields. Its toxicity, mobility and bio-availability are strongly dependent on its oxidation state, Cr(III) and Cr(VI). Hexavalent form Cr(VI) is a known carcinogen with many harmful effects on living organisms, on the other hand trivalent Cr(III) form is an important micronutrient necessary for lipid metabolism. Contamination of the environment by Cr may come from anthropogenic industrial pollution or from naturally enriched sites, especially ultramafic rocks and their derived soils. Environmental conditions of soils and water represent a very complex system, which makes reliable assessment of its fate and potential toxicity and transport a really difficult task. A number of studies have been performed to describe Cr behaviour in these systems, as well as to optimize its determination, especially speciation methods. The main objective of this contribution is to summarize and present the today’s knowledge about the occurrence, speciation, and behaviour of Cr in soil environment, with a specific emphasis to description of differences between naturally enriched and anthropogenically contaminated soils.
机译:铬(Cr)是过去几十年来在许多专家领域中检测到的非常重要的元素。它的毒性,迁移率和生物利用度在很大程度上取决于其氧化态Cr(III)和Cr(VI)。六价铬形式的六价铬是一种已知的致癌物质,对生物体具有许多有害影响,另一方面,三价铬形式的三价铬是脂质代谢所必需的重要微量营养素。铬对环境的污染可能来自人为的工业污染或自然富集的场所,特别是超镁铁质岩石及其衍生的土壤。土壤和水的环境条件代表了一个非常复杂的系统,这使得对其命运和潜在毒性以及运输的可靠评估变得非常困难。已经进行了许多研究来描述这些系统中Cr的行为,并优化其测定,尤其是形态分析方法。这项贡献的主要目的是总结和介绍当今有关土壤环境中Cr的发生,形态和行为的知识,并特别强调描述自然富集和人为污染的土壤之间的差异。

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